Chemical name GLYCIDYL METHACRYLATE, (GMA)
Chemical formula

CH2=C(CH3)COOCH2CH(O)CH2

Concentration

98.5% or greater (Normal concentration is 100%)

Inhibitor 100±10 ppm
CAS Number 106-91-2
EINECS # 203-441-9
HS code 2916140000
Chemical name GLYCIDYL METHACRYLATE, (GMA)
HS code 2916140000
Chemical formula

CH2=C(CH3)COOCH2CH(O)CH2

Concentration

98.5% or greater (Normal concentration is 100%)

Inhibitor 100±10 ppm
CAS Number 106-91-2
EINECS # 203-441-9

Glycidyl Methacrylate (GMA)

Glycidyl Methacrylate (GMA) is an ester of Methacrylic Acid and Glycidol. The characteristic of the property of Glycidyl Methacrylate (GMA) is its dual functionality – due to the methacrylic and epoxy groups. This gives it the possibility to combine the chemical properties of acrylates, reacting with styrene, by acrylates or by ethylene, and epoxies. The epoxy group of Glycidyl Methacrylate (GMA) is capable of different chemical transformations both in the monomer and in the polymers.

Glycidyl Methacrylate (GMA)  reacts with different substances (amines, phenols, ketones, carbonaceous acids, which contain halogen and others). It makes it possible to synthesize many new chemical connections. Small additives of Glycidyl Methacrylate (GMA) and its derivatives to different polymeric materials improve their mechanical, optical, adhesive characteristics, chemical, and atmospheric durability.

Product type: Methacrylate Monomer

Applications areas:

  • Glycidyl Methacrylate (GMA) is used for improving the quality and reaching the optimum performance properties of varnishes and paints, natural rubbers, latexes, sealing compounds, industrial protective coatings, synthetic fibers, paper, thermoplastics, structural and ion-exchange materials, used in polygraphy, automobile construction, radio engineering and microelectronics, biotechnology and in medicine.

It is applied in the production of:

  • Coating resins
  • Adhesives
  • Textile finishes
  • Ion exchange resins
  • Modifications
  • Electrification resists
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Chemical Properties:

  • Purity
    min. 98.5.0 %
  • Acid Value
    max. 0.5%
  • Water content
    max. 0.1 %
  • Color APHA
    max. 30
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Physical Properties:

  • Appearance
    Transparent clear
  • Physical form
    liquid
  • Odor
    -
  • Molecular weight
    142.15 g/mol
  • Polymer Tg
    -
  • Tg
    -
  • Density
    1.073~1.083 g/cm at 20 °C
  • Boiling Point
    189 °C at 760 mmHg
  • Freezing Point
    - 41.5 °C
  • Flash point
    76 °C
  • Melting Point
    - 65 °C
  • Viscosity
    2.14mPa・s at 25℃
  • Vapor Point
    1,333 Pa, 10mmHg at 75℃

To prevent polymerization, Glycidyl Methacrylate (GMA) should always be stored in air, and never under inert gases. For the stabilizer to work effectively, oxygen is required. It must contain a stabilizer. Storage temperature should not exceed 35 °C. Under these conditions, the storage stability of one year can be expected. To minimize the likelihood of congestion, the storage procedure should strictly follow the principle of “first come, first come”. For a long shelf life of more than 4 weeks, it is advisable to replenish the oxygen content. Over time, the content of ethylene glycol diacrylate slowly increases. If this component is relevant to your process, Glycidyl Methacrylate (GMA) should be used within 12 months of receipt. The preferred material for tanks and pipes is stainless steel. Carbon steel is also used, although rust formation may occur, which will lead to a problem with product quality (color). Iron (III) -ion has been shown to be a weak initiator of polymerization. If carbon steel is to be used, special treatment should be used to prepare the tank for use. Storage tanks, pumps, and pipes must be earthed. Store containers with Glycidyl Methacrylate (GMA) tightly closed in a cool, dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Storage & Handling:

To prevent polymerization, Glycidyl Methacrylate (GMA) should always be stored in air, and never under inert gases. For the stabilizer to work effectively, oxygen is required. It must contain a stabilizer. Storage temperature should not exceed 35 °C. Under these conditions, the storage stability of one year can be expected. To minimize the likelihood of congestion, the storage procedure should strictly follow the principle of “first come, first come”. For a long shelf life of more than 4 weeks, it is advisable to replenish the oxygen content. Over time, the content of ethylene glycol diacrylate slowly increases. If this component is relevant to your process, Glycidyl Methacrylate (GMA) should be used within 12 months of receipt. The preferred material for tanks and pipes is stainless steel. Carbon steel is also used, although rust formation may occur, which will lead to a problem with product quality (color). Iron (III) -ion has been shown to be a weak initiator of polymerization. If carbon steel is to be used, special treatment should be used to prepare the tank for use. Storage tanks, pumps, and pipes must be earthed. Store containers with Glycidyl Methacrylate (GMA) tightly closed in a cool, dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Safety

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Avoid exposure - obtain special instructions before use. Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge.

Note

The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may affect the processing and application of our product, these data do not relieve processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any descriptions, drawings, photographs, data, proportions, weights, etc. given herein may change without prior information and do not constitute the agreed contractual quality of the product. It is the responsibility of the recipient of our products to ensure that any proprietary rights and existing laws and legislation are observed.

It packed in drums.

Delivery conditions

It packed in drums.